Publications

Research

2024

45 "Reactivity of Superbasic Carbanions Generated via Reductive Radical-Polar Crossover in the Context of Photoredox Catalysis"

revison submitted ACIE 2024

Sascha Grotjahn, Christina Graf, Jan Zelenka, Aryaman Pattanaik, Lea Müller, Roger Jan Kutta, Julia Rehbein, Jana Roithová, Ruth M. Gschwind, Patrick Nuernberger, and Burkhard König*

2023

44 Counterion Effect in Cobaltate-Catalyzed Alkene Hydrogenation

Martin Gawron, Franziska Gilch, Daniel Schmidhuber, John A. Kelly, Thomas M. Horsley Downie, Axel Jacobi von Wangelin, Julia Rehbein*, Robert Wolf*

Angew. Chem. Int. Ed., 2024, 63, e2023153; https://doi.org/10.1002/anie.202315381

HOT Paper :)

43 Copper(I) Photocatalyzed Bromonitroalkylation of Olefins: Evidence for Highly Efficient Inner-Sphere Pathways

Alexander Reichle, Magdalena Koch, Hannes Sterzel, Lea-Joy Großkopf, Johannes Floß, Julia Rehbein*, Oliver Reiser*

Angew. Chem. Int. Ed., 2023, DOI: 10.1002/ange.202219086

2022

42 Hydrogen-Bond-Modulated Nucleofugality of SeIII Species to Enable Photoredox-Catalytic Semipinacol Manifolds

Amit K. Dutta, Sooyoung Park, Carina Allacher, Anton Abramov, Philipp Dullinger, Katerina

Kuzmanoska, Daniela Fritsch, Patrick Hitzfeld, Dominik Horinek, Julia Rehbein*, Patrick Nuernberger*, Ruth M. Gschwind*, Alexander Breder*

Angew. Chem. Int. Ed., 2022, accepted, DOI: 10.1002/anie.202208611

41 Efficient Copper-Catalyzed Highly Stereoselective Synthesis of Unprotected C-Acyl Manno-, Rhamno- and Lyxopyranosides

Gordon Jacob Boehlich, Hannes Sterzel, Julia Rehbein*, Nina Schützenmeister*

Chemistry - A European Journal, in production, DOI: 10.1002/chem.202202619

40 Barry Carpenter – Pioneering Physical Organic Chemist, Teacher, Mentor and Friend

Stephanie R. Hare, Allan R. Pinhas, Julia Rehbein, Dean J. Tantillo, and Stephen Wiggins

Journal of Physical Organic Chemistry, in production, DOI: 10.1002/poc.4431

39 Copper(II)-photocatalyzed Decarboxylative Oxygenation of Carboxylic Acids

Alexander Reichle, Hannes Sterzel, Peter Kreitmeier, Remi Fayad, Felix N. Castellano,* Julia Rehbein* and Oliver Reiser*

Chem. Commun., 2022, Advance Article; https://doi.org/10.1039/D2CC00570K; Chemical Communications HOT Articles 2022!

38 Thermoneutral synthesis of spiro-1,4-cyclohexadienes by visible-light-driven dearomatization of benzylmalonates

Quan-Qing Zhao, Julia Rehbein , Oliver Reiser

Green Chem., 2022, Advance Articlehttps://doi.org/10.1039/d1gc04686a

2021

37 Heck-Type Coupling of Fused Bicyclic Vinylcyclopropanes: Synthesis of 1,2-Dihydropyridines, 2,3-Dihydro-1H-Azepines, 1,4-Cyclohexadienes, 2H-Pyrans, and 1,3-Butadienes

Nikolai Wurzer, Urszula Klimczak, Tobias Babl, Sebastian Fischer, Ricardo A. Angnes, Dominik Kreutzer, Aryman Pattanaik, Julia Rehbein, Oliver Reiser

ACS Catal. 2021, 11, 12019−12028. https://doi.org/10.1021/acscatal.1c02564

36 Mechanistic investigations towards a successful PET with Breslow-Intermediates
Jenny Phan, Julia Rehbein* ChemRxiv. Preprint. https://doi.org/10.26434/chemrxiv.14061392.v1

35 Hole-mediated PhotoRedox Catalysis: Tris(p-substituted)biarylaminium Radical Cations as Tunable, Precomplexing and Potent Photooxidants
ShangzeWu, JonasŽurauskas, Michał Domański, Patrick S. Hitzfeld, ValeriaButera, Daniel J. Scott, Julia Rehbein,

Ajeet Kumar, Erling Thyrhaug, Jürgen Hauer, Joshua P.Barham, Organic Chemistry frontiers; QO-RES-12-2020-001609.R1

34 Value-added chemicals from biomass-derived furans: radical functionalisations of 5-chloromethylfurfural (CMF) by metal-free ATRA reactions
Rajesh Dasi, Daniel Schmidhuber, Lisa Marie Gronbach, Julia Rehbein* and Malte Brasholz* Org. Biomol. Chem. 2021, Advance Article https://doi.org/10.1039/D1OB00013F

2020
33 Diels–Alder reactions and electrophilic substitutions with atypical regioselectivity enable functionalization of terminal rings of anthracene
Vinh Ngoc Huynh, Michael Leitner, Aditya Bhattacharyya, Lisa Uhlstein, Peter Kreitmeier, Patrick Sakrausky, Julia Rehbein* & Oliver Reiser*, Commun Chem 2020 , 3, 158. https://doi.org/10.1038/s42004-020-00407-9

2019
32 Photoorganocatalytic aerobic oxidative amine dehydrogenation / super acid‐mediated Pictet‐Spengler cyclization: synthesis of cis‐1,3‐diaryl tetrahydroisoquinolines
Lisa-Natascha Unkel, Simon Malcherek, Eva Schendera, Frank Hoffmann, Julia Rehbein*, Malte Brasholz * Adv. Synth. Cat., 2019, 361, 2870-2876; https://doi.org/10.1002/adsc.201900165
31 Synthesis and characterisation of acarboxynitrobenzyl photocaged L-aspartates for applications in time-resolved structural biology
John J. Zaitsev-Doyle, Anke Puchert, Yannik Pfeifer, Hao Yan, Briony A. Yorke, Henrike M. Müller-Werkmeister, Charlotte Uetrecht, Julia Rehbein, Nils Huse, Arwen R. Pearson * and Marta Sans RSC Adv., 2019, 9, 8695. DOI: 10.1039/c9ra00968j

2018
30 Visible Light‐Mediated Synthesis of Enantiopure γ‐Cyclobutane Amino and 3‐(Aminomethyl)‐5‐phenylpentanoic Acids
Sabine Kerres, Eva Plut, Simon Malcherek, Julia Rehbein*, Oliver Reiser* Adv. Synth. Catal. https://doi.org/10.1002/adsc.201801413
29 Development of an Alkyne-de Mayo Reaction for the Synthesis of Medium-Sized Carbacycles and Cyclohepta[b]indoles
David Tymann, Dina Christina Tymann, Ulf Bednarzick, Ljuba Iovkova-Berends, Julia Rehbein, Martin Hiersemann Angew. Chem. Int. Ed. 2018, 130, 15779-15783, https://doi.org/10.1002/ange.201808578
28 NHC-stabilzed radicals in the formal hydroacylation of alkynes
Jenny Phan, Stephanie-M. Ruser, Kirsten Zeitler, Julia Rehbein* EJOC 2018, 2-3, 557-561. https://doi.org/10.1002/ejoc.201801185
27 Synthesis of aryl sulfides via radical-radical cross-coupling of electron-rich arenes using visible light photoredox catalysis
Amrita Das, Mitasree Maity, Simon Malcherek, Julia Rehbein*, and Burkhard König* Beilstein J. Org. Chem. 2018, 14, 2520–2528. doi:10.3762/bjoc.14.228
26 Fluorine as a traceless Diecting Group for the Regiodivergent Synthesis of Indoles and Tryptophanes
Anna Andries-Ulmer, Christoph Brunner, Julia Rehbein*, and Tanja Gulder* J. Am. Chem. Soc. 2018 , 140, 13034-13041, DOI: 10.1021/jacs.8b08350
25 Ir(ppy)3-Catalyzed, Visible-Light-Mediated Reaction of a-Chloro Cinnamates with Enol Acetates: An Apparent Halogen Paradox
Assik Thomas Föll, Julia Rehbein, and Oliver Reiser* Org. Lett. 2018, 20 (18), 5794–5798, doi: 10.10021/acs.orglett.8b02484
24 Visible-Light-Accelerated Copper(II)-Catalyzed Regio- and Chemoselective Oxo-Azidation of Vinyl Arenes
Assik Hossain, Adiyala Vidyasagar, Christian Eichinger, Christian Lankes, Jenny Phan, Julia Rehbein*, and Oliver Reiser* Angew. Chem. Int. Ed. 2018, 57, 8288-8292, doi: 10.1002/anie.201801678
23 Panta rhei - Wie wir chemische Rekationen verstehen und beschreiben
Julia Rehbein* Blick in die Wissenschaft 2018, printed in the autumn issue

2017
22 Mechanistic and Synthetic Investigations on the Dual Selenium-Acid/Photoredox Catalysis in the Context of the Aerobic Dehydrogenative Lactonization of Alkenoic Acids; Stefan Ortgies, R. Rieger, K. Rode, K. Koszinowski, J. Kind, Ch. M. Thiele, J. Rehbein, A. Breder, ACS Catal., 2017, 7, 7578.
21 Photoredox-induced radical 6-exo-trig cyclisations onto the indole nucleus: aromative versus dearomative pathways
Dirk Alpers, Malte Brasholz*, Julia Rehbein* Eur. J. Org. Chem. 2017, 15, 2186.

2016
20 Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents
Michael Brown, Ravi Kumar, Julia Rehbein, Thomas Wirth*
Chem. Eur. J. 2016, 22, 4030–4035.

2015
19 Chemistry in Motion - Off the MEP
J. Rehbein, B. Wulff Tetrahedron Lett. 2015, 56, 6931.
18 Synthesis and Structural Analysis of DOTAZA (1,4,7,10-Tetra-azacyclododecane-1,4,7,10-tetra-azidoethylacetic acid) Complexes
Ella Kriemen, Malte Holzapfel, Erik Ruf, Julia Rehbein,Wolfgang Maison*
Eur. J. Inorg. Chem. 2015, 32, 5368–5378.
17 NHC-Catalyzed Benzoin Condensation – Is It All Down to the Breslow Intermediate?
Julia Rehbein*, Stephanie M. Ruser, Jenny Phan
Chem. Sci. 2015, 6, 6013–6018.
16 Studies towards the synthetic applicability of biocatalytic allylic oxidations with the lyophilisate of Pleurotus sapidus
Verena Weidmann, Serge Kliewer, Marco Sick, Sergej Bycinskij, Margarethe Kleczka, Julia Rehbein, Axel G. Griesbeck, Holger Zorn, Wolfgang Maison
Journal of Molecular Catalysis B: Enzymatic 2015, 121, 15–21.

2013
15 Elucidation of the regio- and chemoselectivity of enzymatic allylic oxidations with Pleurotus sapidus - conversion of selected spirocyclic terpenoids and computational analysis
V. Weidmann, M. Schaffrath, H. Zorn, J. Rehbein, W. Maison Beilstein Journal of Organic Chemistry 2013, 9, 2233–2241 .

14 Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers from 1912 to 2012: 100 Years of Electrophilic Catalysis
Julia Rehbein, Martin Hiersemann
Synthesis 45, 1121-1159 (2013)

2012
13 Novel Oxidative Rearrangements Using Hypervalent Iodine Reagents
Fateh V. Singh, Julia Rehbein, Thomas Wirth
Chemistry Open 1, 245-250 (2012)
12 Catalytic Asymmetric Gosteli-Claisen Rearrangement (CAGC)
Julia Rehbein, Martin Hiersemann -/- Herausgeber: Mathias Christmann, Stefan Bräse
Asymmetric Synthesis. More Methods and Applications 157-162 (2012), Verlag: Wiley-VCH, Weinheim

2011
11 Total Synthesis of Natural and Non-Natural Δ5,6Δ12,13-Jatrophane Diterpenes and Their Evaluation as MDR Modulators
Christoph Schnabel, Katja Sterz, Henrik Müller, Julia Rehbein, Michael Wiese, Martin Hiersemann
Journal of Organic Chemistry 2011, 76, 512-522.
10 Integration of catalysis and analysis is the key: rapid and precise investigation of the catalytic asymmetric Gosteli-Claisen rearrangement
Johannes Troendlin, Julia Rehbein, Martin Hiersemann, Oliver Trapp Journal of the American Chemical Society 2011, 133, 16444-16450.
9 Gosteli-Claisen Rearrangement of Propargyl Vinyl Ethers: Cascading Molecular Rearrangements
Annika Gille, Julia Rehbein, Martin Hiersemann Organic Letters 2011, 13, 2122-2125.
8 Do we fully understand what controls chemical selectivity?
Julia Rehbein*, Barry K. Carpenter Physical Chemistry Chemical Physics 2011, 13, 20906-20922.

2009
7 2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propanebis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
Julia Rehbein, Markus Schürmann, Hans Preut, Martin Hiersemann
Acta Crystallographica, Section E: Structure Reports Online E65, 2009, 737
6 Gosteli-Claisen Rearrangement: Substrate Synthesis, Simple Diastereoselectivity, and Kinetic Studies
Julia Rehbein, Sabine Leick, Martin Hiersemann Journal of Organic Chemistry 2009, 74, 1531–1540.
5 Gosteli-Claisen Rearrangement: DFT Study of Substituent-Rate Effects
Julia Rehbein, Martin Hiersemann Journal of Organic Chemistry 2009, 74, 4336–4342
4 Gosteli-Claisen Rearrangement: Rate Effects of Substituents, Solvents and Catalysts. A Combined Experimental and Theoretical Study
Julia Rehbein -/- Betreuer: Martin Hiersemann
Dissertation, Dortmund (2009)

2007
3 Organocatalytic Claisen Rearrangement: Theory and Experiment
Martin Kirsten, Julia Rehbein, Martin Hiersemann, Thomas Strassner Journal of Organic Chemistry 2007, 72, 4001-4011.
2 Mechanistic aspects of the aliphatic Claisen rearrangement
Julia Rehbein, Martin Hiersemann -/- Herausgeber: Martin Hiersemann, Udo Nubbemeyer
The Claisen Rearrangement, Methods and Applications 2007, 525-557

2004
1 Enantioselective synthesis of the C-14 to C-5 cyclopentane segment of jatrophane diterpenes
Hannes Helmboldt, Julia Rehbein, Martin Hiersemann
Tetrahedron Letters 2004, 45, 289-292.